\u4e8c\u7532\u57fa\u6c27\u5316\u9521\uff08Dimethyltin Oxide\uff09\uff0c\u5316\u5b66\u5f0fC2H6OSn\uff0c\u4f5c\u4e3a\u4e00\u79cd\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u5728\u5316\u5b66\u5408\u6210\u548c\u5de5\u4e1a\u5e94\u7528\u4e2d\u626e\u6f14\u7740\u91cd\u8981\u89d2\u8272\u3002\u5c3d\u7ba1\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u4e0d\u50cf\u65e0\u673a\u9521\u5316\u5408\u7269\u90a3\u6837\u5177\u6709\u5e7f\u6cdb\u7684\u57fa\u7840\u5316\u5b66\u53cd\u5e94\u65b9\u7a0b\u5f0f\uff0c\u4f46\u5b83\u5728\u7279\u5b9a\u6761\u4ef6\u4e0b\u4ecd\u80fd\u53c2\u4e0e\u4e00\u7cfb\u5217\u5316\u5b66\u53cd\u5e94\uff0c\u5c24\u5176\u662f\u5728\u6709\u673a\u5408\u6210\u3001\u50ac\u5316\u4f5c\u7528\u4ee5\u53ca\u4e0e\u5176\u4ed6\u5316\u5b66\u7269\u8d28\u7684\u76f8\u4e92\u4f5c\u7528\u4e2d\u3002\u4e0b\u9762\u5217\u4e3e\u51e0\u4e2a\u4e0e\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u76f8\u5173\u7684\u5316\u5b66\u53cd\u5e94\u65b9\u7a0b\u5f0f\uff0c\u4ee5\u5c55\u793a\u5176\u5728\u5b9e\u9a8c\u5ba4\u548c\u5de5\u4e1a\u4e0a\u7684\u5e94\u7528\u3002<\/p>\n
\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u7684\u5408\u6210\u901a\u5e38\u6d89\u53ca\u4e8c\u7532\u57fa\u9521\u5316\u5408\u7269\u4e0e\u6c27\u6c14\u6216\u6c27\u5316\u5242\u7684\u53cd\u5e94\u3002\u4f8b\u5982\uff0c\u7531\u4e8c\u7532\u57fa\u9521\u4e8c\u6c2f\u5316\u7269\uff08(CH3)2SnCl2\uff09\u4e0e\u6c27\u6c14\u53cd\u5e94\u751f\u6210\uff1a<\/p>\n
(3)22+2\u2192(3)2+22<\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>C<\/span>l<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>O<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>\u2192<\/span><\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>O<\/span>+<\/span><\/span>2<\/span>C<\/span>l<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n
\u7136\u800c\uff0c\u5b9e\u9645\u7684\u5408\u6210\u8def\u5f84\u53ef\u80fd\u4f1a\u66f4\u52a0\u590d\u6742\uff0c\u6d89\u53ca\u5230\u50ac\u5316\u5242\u548c\u7279\u5b9a\u7684\u53cd\u5e94\u6761\u4ef6\u3002<\/p>\n
\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u5728\u6709\u673a\u5408\u6210\u4e2d\u4f5c\u4e3a\u50ac\u5316\u5242\u4f7f\u7528\uff0c\u53c2\u4e0e\u9187\u3001\u916e\u3001\u916f\u7b49\u5316\u5408\u7269\u7684\u5408\u6210\u6216\u8f6c\u5316\u3002\u4f8b\u5982\uff0c\u5b83\u53ef\u4ee5\u50ac\u5316\u9187\u4e0e\u9178\u9150\u5f62\u6210\u916f\u7684\u53cd\u5e94\uff1a<\/p>\n
+()2\u2192(3)2\u2032+2<\/span>RO<\/span>H<\/span>+<\/span><\/span>(<\/span>RCOO<\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>(<\/span>C<\/span>H<\/span>3<\/span>\u200b<\/span><\/span>)2<\/span>\u200b<\/span><\/span><\/span>S<\/span>n<\/span>O<\/span><\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>RCOO<\/span>R<\/span>\u2032<\/span><\/span><\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span><\/span><\/span><\/span><\/span><\/p>\n
\u8fd9\u91ccR\u548cR’\u4ee3\u8868\u4e0d\u540c\u7684\u70f7\u57fa\u6216\u82b3\u57fa\u3002<\/p>\n
\u5728\u6c34\u7684\u5b58\u5728\u4e0b\uff0c\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u53ef\u4ee5\u53d1\u751f\u6c34\u89e3\uff0c\u4ea7\u751f\u76f8\u5e94\u7684\u9187\u76d0\u548c\u9178\uff1a<\/p>\n
(3)2+2\u2192(3)2()2+2<\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>O<\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span>\u2192<\/span><\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>(<\/span>O<\/span>H<\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>H<\/span>O<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n
\u5b9e\u9645\u4e0a\uff0c\u6c34\u89e3\u8fc7\u7a0b\u53ef\u80fd\u66f4\u4e3a\u590d\u6742\uff0c\u4ea7\u7269\u4e5f\u53ef\u80fd\u56e0\u53cd\u5e94\u6761\u4ef6\u800c\u5f02\u3002<\/p>\n
\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u53ef\u4ee5\u4e0e\u5f3a\u9178\u53cd\u5e94\uff0c\u5982\u76d0\u9178\u6216\u785d\u9178\uff0c\u4ea7\u751f\u76f8\u5e94\u7684\u76d0\u548c\u6c34\uff1a<\/p>\n
(3)2+2\u2192(3)22+2<\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>O<\/span>+<\/span><\/span>2<\/span>H<\/span>Cl<\/span>\u2192<\/span><\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>C<\/span>l<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>H<\/span>2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>O<\/span><\/span><\/span><\/span><\/span><\/p>\n
\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u53ef\u4ee5\u4e0e\u67d0\u4e9b\u91d1\u5c5e\u76d0\u53cd\u5e94\uff0c\u8fdb\u884c\u91d1\u5c5e\u79bb\u5b50\u7684\u7f6e\u6362\uff0c\u751f\u6210\u65b0\u7684\u6709\u673a\u91d1\u5c5e\u5316\u5408\u7269\u3002\u4f8b\u5982\uff0c\u4e0e\u94dc\u53cd\u5e94\u53ef\u80fd\u4ea7\u751f\u4e8c\u7532\u57fa\u9521\u4e8c\u76d0\uff1a<\/p>\n
(3)2+4\u2192(3)24+<\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>O<\/span>+<\/span><\/span>C<\/span>u<\/span>S<\/span>O<\/span>4<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>\u2192<\/span><\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>S<\/span>O<\/span>4<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>C<\/span>u<\/span>O<\/span><\/span><\/span><\/span><\/span><\/p>\n
\u7136\u800c\uff0c\u4e0a\u8ff0\u53cd\u5e94\u65b9\u7a0b\u5f0f\u4ec5\u4e3a\u793a\u4f8b\uff0c\u5b9e\u9645\u53cd\u5e94\u53ef\u80fd\u53d7\u5230\u53cd\u5e94\u6761\u4ef6\u3001\u50ac\u5316\u5242\u548c\u526f\u53cd\u5e94\u7684\u5f71\u54cd\u3002<\/p>\n
\u5728\u67d0\u4e9b\u6761\u4ef6\u4e0b\uff0c\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u53ef\u4ee5\u4f5c\u4e3a\u8fd8\u539f\u5242\uff0c\u8fd8\u539f\u67d0\u4e9b\u5316\u5408\u7269\u3002\u4f8b\u5982\uff0c\u5b83\u53ef\u4ee5\u8fd8\u539f\u67d0\u4e9b\u91d1\u5c5e\u79bb\u5b50\uff1a<\/p>\n
(3)2+2+\u2192(3)22++2(\u22121)+<\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>O<\/span>+<\/span><\/span>2<\/span>M<\/span>n<\/span>+<\/span><\/span><\/span><\/span><\/span><\/span><\/span>\u2192<\/span><\/span>(<\/span>C<\/span>H<\/span>3<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>)2<\/span><\/span><\/span>\u200b<\/span><\/span><\/span><\/span><\/span>S<\/span>n<\/span>2+<\/span><\/span><\/span><\/span><\/span><\/span><\/span>+<\/span><\/span>2<\/span>M<\/span>(<\/span>n<\/span>\u2212<\/span>1)<\/span>+<\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/span><\/p>\n
\u8fd9\u91cc\u7684M\u4ee3\u8868\u91d1\u5c5e\u79bb\u5b50\uff0cn\u8868\u793a\u5176\u6c27\u5316\u6001\u3002<\/p>\n
\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u7684\u5316\u5b66\u53cd\u5e94\u65b9\u7a0b\u5f0f\u5c55\u793a\u4e86\u5176\u5728\u5316\u5b66\u5408\u6210\u3001\u50ac\u5316\u4ee5\u53ca\u91d1\u5c5e\u79bb\u5b50\u7f6e\u6362\u7b49\u65b9\u9762\u7684\u591a\u529f\u80fd\u6027\u3002\u7136\u800c\uff0c\u7531\u4e8e\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u7684\u7279\u6027\u548c\u53cd\u5e94\u6761\u4ef6\u7684\u591a\u6837\u6027\uff0c\u5b9e\u9645\u5e94\u7528\u4e2d\u53ef\u80fd\u9700\u8981\u6839\u636e\u5177\u4f53\u76ee\u6807\u548c\u53cd\u5e94\u4f53\u7cfb\u6765\u8c03\u6574\u53cd\u5e94\u6761\u4ef6\uff0c\u5305\u62ec\u6e29\u5ea6\u3001\u538b\u529b\u3001\u6eb6\u5242\u9009\u62e9\u548c\u50ac\u5316\u5242\u4f7f\u7528\u3002\u6b64\u5916\uff0c\u7531\u4e8e\u4e8c\u7532\u57fa\u6c27\u5316\u9521\u53ef\u80fd\u5177\u6709\u7684\u6bd2\u6027\uff0c\u6240\u6709\u5b9e\u9a8c\u90fd\u5e94\u5728\u9002\u5f53\u7684\u4e2a\u4eba\u9632\u62a4\u548c\u5b89\u5168\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u9075\u5faa\u5b9e\u9a8c\u5ba4\u5b89\u5168\u51c6\u5219\u548c\u5316\u5b66\u54c1\u5904\u7406\u89c4\u5b9a\u3002<\/p>\n
\u6269\u5c55\u9605\u8bfb\uff1a<\/p>\n
bismuth neodecanoate\/CAS 251-964-6 \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n
stannous neodecanoate catalysts \u2013 Amine Catalysts (newtopchem.com)<\/u><\/a><\/p>\n
DMCHA – morpholine<\/u><\/a><\/p>\n
N-Methylmorpholine – morpholine<\/u><\/a><\/p>\n
Polycat 41 catalyst CAS10294-43-5 Evonik Germany \u2013 BDMAEE<\/u><\/a><\/p>\n